Transmittance


Transmittance of the surface of a material is its effectiveness in transmitting radiant energy. It is the fraction of incident electromagnetic power that is transmitted through a sample, in contrast to the transmission coefficient, which is the ratio of the transmitted to incident electric field.
Internal transmittance refers to energy loss by absorption, whereas transmittance is that due to absorption, scattering, reflection, etc.

Mathematical definitions

Hemispherical transmittance

Hemispherical transmittance of a surface, denoted T, is defined as
where
Spectral hemispherical transmittance in frequency and spectral hemispherical transmittance in wavelength of a surface, denoted Tν and Tλ respectively, are defined as
where
Directional transmittance of a surface, denoted TΩ, is defined as
where
Spectral directional transmittance in frequency and spectral directional transmittance in wavelength of a surface, denoted Tν,Ω and Tλ,Ω respectively, are defined as
where
By definition, internal transmittance is related to optical depth and to absorbance as
where
The Beer–Lambert law states that, for N attenuating species in the material sample,
or equivalently that
where
Attenuation cross section and molar attenuation coefficient are related by
and number density and amount concentration by
where NA is the Avogadro constant.
In case of uniform attenuation, these relations become
or equivalently
Cases of non-uniform attenuation occur in atmospheric science applications and radiation shielding theory for instance.

SI radiometry units