In physics, a charge carrier is a particle or quasiparticle that is free to move, carrying an electric charge, especially the particles that carry electric charges in electrical conductors. Examples are electrons, ions and holes. In a conducting medium, an electric field can exert force on these free particles, causing a net motion of the particles through the medium; this is what constitutes an electric current. In conducting media, particles serve to carry charge:
In electrolytes, such as salt water, the charge carriers are ions, which are atoms or molecules that have gained or lost electrons so they are electrically charged. Atoms that have gained electrons so they are negatively charged are called anions, atoms that have lost electrons so they are positively charged are called cations. Cations and anions of the dissociated liquid also serve as charge carriers in melted ionic solids. Proton conductors are electrolytic conductors employing positive hydrogen ions as carriers.
In a plasma, an electrically charged gas which is found in electric arcs through air, neon signs, and the sun and stars, the electrons and cations of ionized gas act as charge carriers.
In a vacuum, free electrons can act as charge carriers. In the electronic component known as the vacuum tube, the mobile electron cloud is generated by a heated metal cathode, by a process called thermionic emission. When an electric field is applied strong enough to draw the electrons into a beam, this may be referred to as a cathode ray, and is the basis of the cathode ray tube display widely used in televisions and computer monitors until the 2000s.
In semiconductors, which are the material used to make electronic components like transistors and integrated circuits, behave as if "effective particles" known as electron holes with positive charge move through them, causing electrical properties. The "holes" behave as the traveling vacancies in the valence-band electron population of the semi-conductor and are treated as charge carriers. Electrons and holes are the charge carriers in semiconductors.
It can be seen that in some conductors, such as ionic solutions and plasmas, there are positive and negative charge carriers, so an electric current in them consists of the two polarities of carrier moving in opposite directions. In other conductors, such as metals, there are only charge carriers of one polarity, so an electric current in them just consists of charge carriers moving in one direction.
In semiconductors
There are two recognized types of charge carriers in semiconductors. One is electrons, which carry a negative electric charge. In addition, it is convenient to treat the traveling vacancies in the valence band electron population as a second type of charge carrier, which carry a positive charge equal in magnitude to that of an electron.
Carrier generation and recombination
When an electron meets with a hole, they recombine and these free carriers effectively vanish. The energy released can be either thermal, heating up the semiconductor, or released as photons. The recombination means an electron which has been excited from the valence band to the conduction band falls back to the empty state in the valence band, known as the holes. The holes are the empty state created in the valence band when an electron gets excited after getting some energy to overpass the energy gap.
Majority and minority carriers
The more abundant charge carriers are called majority carriers, which are primarily responsible for current transport in a piece of semiconductor. In n-type semiconductors they are electrons, while in p-type semiconductors they are holes. The less abundant charge carriers are called minority carriers; in n-type semiconductors they are holes, while in p-type semiconductors they are electrons. In an intrinsic semiconductor, which does not contain any impurity, the concentrations of both types of carriers are ideally equal. If an intrinsic semiconductor is doped with a donor impurity then the majority carriers are electrons. If the semiconductor is doped with an acceptor impurity then the majority carriers are holes. Minority carriers play an important role in bipolar transistors and solar cells. Their role in field-effect transistors is a bit more complex: for example, a MOSFET has p-type and n-type regions. The transistor action involves the majority carriers of the source and drain regions, but these carriers traverse the body of the opposite type, where they are minority carriers. However, the traversing carriers hugely outnumber their opposite type in the transfer region, so conventionally the source and drain designation for the carriers is adopted, and FETs are called "majority carrier" devices.
Free carrier concentration is the concentration of free carriers in a doped semiconductor. It is similar to the carrier concentration in a metal and for the purposes of calculating currents or drift velocities can be used in the same way. Free carriers are electrons which have been introduced directly into the conduction band by doping and are not promoted thermally. For this reason electrons will not act as double carriers by leaving behind holes in the other band. In other words, charge carriers are particles/electrons that are free to move.
