Tricyclohexylphosphine


Tricyclohexylphosphine is the tertiary phosphine with the formula P3. Commonly used as a ligand in organometallic chemistry, it is often abbreviated to PCy3, where Cy stands for cyclohexyl. It is characterized by both high basicity and a large ligand cone angle.
Important complexes containing P3 ligands include the 2005 Nobel Prize-winning Grubbs' catalyst and the homogeneous hydrogenation catalyst Crabtree's catalyst.