Satterlyite is a hydroxyl bearing iron phosphate mineral. The mineral can be found in phosphatic shales and was first discovered in the Big Fish River area in Yukon Territory, Canada. Satterlyite is part of the phosphate mineral group. Satterlyite is a transparent, light brown to light yellow mineral with a density of 3.68 g/cm3. The structure of satterlyite is made up of two pairs of face shared, distorted O6 octahedra, linked together by sharing edges to form double chains along the plain. The first satterlyite mineral was discovered in the Big Fish River area in Yukon Territory, westernmost of Canada; by a geologist at Ontario Department of Mines in Canada, Jack Satterly, and the mineral was also named after him.
Composition
Satterlyite has a formula of 2. Studies using the optical absorption spectra show that satterlyite has similar features to different iron bearing minerals with Fe and Fe impurities. EPR studies were also made on the mineral first by turning the satterlyite mineral fine powder then putting it into an EPR quartz tube for measurements. The results from the EPR show a strong line on g=2.0 and another line on g=8.0, thus also showing a presence of ferrous and ferric ions in satterlyite.
Structure
Satterlyite is hydroxyl bearing iron phosphate with a space group P31m. The structure of satterlyite is made up of two pairs of face shared, distorted O6 octahedra, the two faces are linked together by sharing edges to form double chains along the plain. The double chains share ligands with six other double chains to make a 3D network holding three PO4 tetrahedra, linked by the corners to the O6 octahedra. The two O6 Octahedra have different occupancies; the Fe to Mg ratio of the M sites are 0.838:0.162 for the M site and 0.706:0.294 for the M site. The structure contains three H atoms; two are share ligands with two O6 octahedra and the third strongly disordered H atom is bonded to O of the PO4 tetrahedron. Holtedahlite, a mineral that was found in Tingelstadtjern quarry in Norway, with the formula 56 is isostructural with satterlyite. Infrared absorption powder spectra show that satterlyite is different from natural haltedahlite in that there is no carbonate for phosphate substitution. Satterlyite is also structurally related to phosphoellenbergerite, a mineral that was discovered in Modum, Norway; near San Giocomo Vallone Di Gilba, in Western Alps of Italy ; the minerals formula is Mg14526. EPR and optical absorption studies have investigated the iron phosphate mineral satterlyite and gormanite. Results of the optical studies show that both minerals have ferrous and ferric ions. These studies also show that the site symmetry of Fe in satterlyite is tetragonally distorted. However, the Fe ions is tetragonally distorted octahedral. The complex structure of satterlyite is made up of two pairs of face shared, distorted O6 octahedra, linked together by sharing edges to form double chains along .
Physical properties
Satterlyite has a light brown to light yellow color with a light yellow streak and a hardness of 4.5 to 5. It has no trigonal crystal symmetry with a space group P3*1m and no cleavage. The parameters of the mineral are a=11.35 Å and c=5.04 Å and the ratio of a to c is 1:0.444 and a cell volume 562.28 Å3. The mineral is found as one of three habits; aggregated, nodular or radial .
Geologic occurrence
Jack Satterly, a geologist at Ontario Department of Mines in Canada, discovered satterlyite in nodules in shale in the Big Fish River. These nodules were about 10 cm in diameter, some would consist of satterlyite only and others would show satterlyite with quartz, pyrite, wolfeite or maricite. The Commission on New Minerals and Mineral Names approved the name of the mineral. The type specimen is now preserved at the Royal Ontario Museum.
