Pendant group
In IUPAC nomenclature of chemistry, a pendant group or side group is a group of atoms attached to a backbone chain of a long molecule, usually a polymer. Pendant groups are different from pendant chains, as they are neither oligomeric nor polymeric.
For example, the phenyl groups are the pendant groups on a polystyrene chain.
Large, bulky pendant groups such as adamantyl usually raise the glass transition temperature of a polymer by preventing the chains from sliding past each other easily. Short alkyl pendant groups may lower the Tg by a lubricant effect.
