Particle size


Particle size is a introduced for comparing dimensions of solid particles, liquid particles, or gaseous particles. The notion of particle size applies to
colloidal particles, particles in ecology, particles present in granular material, and particles that form a granular material.

Measuring particle size

There are several methods for measuring particle size and particle size distribution. Some of them are based on light, other on ultrasound, or electric field, or gravity, or centrifugation. The use of sieves is a common measurement technique, however this process can be more susceptible to human error and is time consuming. Technology such as dynamic image analysis can make particle size distribution analyses much easier. This approach can be seen in instruments like Retsch Technology's CAMSIZER or the Sympatec QUICPIC series of instruments. They still lack the capability of inline measurements for real time monitoring in production environments. Therefore, inlie imaging devices like the SOPAT system are most efficient.
In all methods the size is an indirect measure, obtained by a model that transforms, in abstract way, the real particle shape into a simple and standardized shape, like a sphere or a cuboid, where the size parameter makes sense. Exception is the mathematical morphology approach, where no shape hypothesis is necessary.
Definition of the particle size for an ensemble of particles presents another problem. Real systems are practically always polydisperse, which means that the particles in an ensemble have different sizes. The notion of particle size distribution reflects this polydispersity. There is often a need for a certain average particle size for the ensemble of particles.

Expressions for sphere size

The particle size of a spherical object can be unambiguously and quantitatively defined by its diameter. However, a typical material object is likely to be irregular in shape and non-spherical. The above quantitative definition of particle size cannot be applied to non-spherical particles. There are several ways of extending the above quantitative definition to apply to non-spherical particles. Existing definitions are based on replacing a given particle with an imaginary sphere that has one of the properties identical with the particle.
;Volume-based particle size: Volume-based particle size equals the diameter of the sphere that has the same volume as a given particle. Typically used in sieve analysis, as shape hypothesis.
;Area-based particle size: Area-based particle size equals the diameter of the sphere that has the same surface area as a given particle. Typically used in optical granulometry techniques.

Indirect measure expressions

In some measures the size can't be obtained, only calculated as a function of another dimensions and parameters. Illustrating below by the main cases.
;Weight-based particle size: Weight-based particle size equals the diameter of the sphere that has the same weight as a given particle. Useful as hypothesis in centrifugation and decantation, or when the number of particles can be estimated. This formula is only valid when all particles have the same density.
;Aerodynamic particle size: Hydrodynamic or aerodynamic particle size equals the diameter of the sphere that has the same drag coefficient as a given particle.

International conventions

There is an international standard on presenting various characteristic particle sizes, the ISO 9276. This set of various average sizes includes median size, geometric mean size, average size. In the selection of specific small-size particles is common the use of ISO 565 and ISO 3310-1 to the choice of mesh size.

Colloidal particle

In Materials science and Colloidal chemistry, the term colloidal particle is about a small amount of matter having size typical for colloids and with a clear phase boundary. The dispersed-phase particles have a diameter between approximately 1 and 1000 nanometers. Colloids are heterogeneous in nature. Invisible to the naked eye, and always move in a zig-zag motion known as the Brownian motion. The scattering of light by colloidal particles is known as Tyndall effect.