Octafluorocyclobutane


Octafluorocyclobutane, or perfluorocyclobutane, C4F8, is an organofluorine compound which enjoys several niche applications. It is related to cyclobutane by replacement of all C–H bonds with C–F bonds. Octafluorocyclobutane is produced by the dimerization of tetrafluoroethylene and the reductive coupling of 1,2-dichloro-1,1,2,2-tetrafluoroethane.

Applications

In the production of semiconductor materials and devices, octafluorocyclobutane serves as a deposition gas and etchant. It has also been investigated as a refrigerant in specialised applications, as a replacement for ozone depleting chlorofluorocarbon refrigerants. Exploiting its volatility and chemical inertness, octafluorocyclobutane may be found in some aerosolized foods. It is listed by the Codex Alimentarius under number 946. It is investigated as a possible replacement for sulfur hexafluoride as a dielectric gas.

Appendix

Its critical point is at 115.3 °C and 2.79 MPa.