Nickel electroplating


Nickel electroplating is a technique of electroplating a thin layer of nickel onto a metal object. The nickel layer can be decorative, provide corrosion resistance, wear resistance, or used to build up worn or undersized parts for salvage purposes.

Overview

Nickel electroplating is a process of depositing nickel onto a metal part. Parts to be plated must be clean and free of dirt, corrosion, and defects before plating can begin. To clean and protect the part during the plating process, a combination of heat treating, cleaning, masking, pickling, and etching may be used. Once the piece has been prepared it is immersed into an electrolyte solution and is used as the cathode. The nickel anode is dissolved into the electrolyte to form nickel ions. The ions travel through the solution and deposit on the cathode.

Types and chemistry

Watts baths

Watts nickel plating baths can deposit both bright and semi-bright nickel. Bright nickel is typically used for decorative purposes and corrosion protection. Semi-bright deposits are used for engineering applications where high corrosion resistance, ductility or electrical conductivity is important, and a high luster is not required.

Bath Composition

Operating conditions

Type of the added brighteners and their concentrations determine the deposit appearance: brilliant, bright, semi-bright, satin.

Nickel sulfamate

Sulfamate nickel plating is used for many engineering applications. It is deposited for dimensional corrections, abrasion and wear resistance, high efficiency coating and corrosion protection. It is also used as an undercoat for chromium.

Bath composition

Operating conditions

All-Chloride solutions allow for the deposition of thick nickel coatings. They do this because they run at low voltages. However, the deposition has high internal stresses.
Chemical nameFormulaBath concentration
Nickel chlorideNiCl2·6H2O30–40 oz/gal
Boric acidH3BO34–4.7 oz/gal

Sulfate-chloride

A Sulfate-Chloride bath operates at lower voltages than a Watts bath and provide a higher rate of deposition. Although internal stresses are higher than the Watts bath, they are lower than that of an all-chloride bath.
Chemical nameFormulaBath concentration
Nickel sulfateNiSO4·6H2O20–30 oz/gal
Nickel chlorideNiCl2·6H2O20–30 oz/gal
Boric acidH3BO34–6 oz/gal

All-sulfate

An all-sulfate solution is used for electro-depositing nickel where the anodes are insoluble. For example, plating the insides of steel pipes and fittings may require an anode.
Chemical nameFormulaBath concentration
Nickel sulfateNiSO4·6H2O30–53 oz/gal
Boric acidH3BO34–6 oz/gal

Hard nickel

A hard nickel solution is used when a high tensile strength and hardness deposit is required.
Chemical nameFormulaBath concentrationMetric
Nickel sulfateNiSO4·6H2O24 oz/gal179.7g/L
Ammonium chlorideNH4Cl3.3 oz/gal24.7 g/L
Boric acidH3BO34 oz/gal29.96 g/L

Black nickel

Black nickel plating is typically plated on brass, bronze, or steel in order to produce a non-reflective surface. This type of plating is used for decorative and military purposes and does not offer much protection.
Chemical nameFormulaBath concentration
Nickel ammonium sulfateNiSO4·2SO4·6H2O8 oz/gal
Zinc sulfateZnSO41.0 oz/gal
Sodium thiocyanateNaCNS2 oz/gal

Applications

Decorative coating

Decorative bright nickel is used in a wide range of applications. It offers a high luster finish, corrosion protection, and wear resistance. In the automotive industry bright nickel can be found on bumpers, rims, exhaust pipes and trim. It is also used for bright work on bicycles and motorcycles. Other applications include hand tools and household items such as lighting and plumbing fixtures, wire racks, firearms, and appliances.

Engineering applications

Engineering nickel is used where brightness is not desired. Non decorative applications provide wear and corrosion protection as well as low-stress buildups for dimensional recovery. The method can be used for making nanocomposite wear resistance coatings.