Lamprophyre
Lamprophyres = "bright" and φύρω are uncommon, small volume ultrapotassic igneous rocks primarily occurring as dikes, lopoliths, laccoliths, stocks and small intrusions. They are alkaline silica-undersaturated mafic or ultramafic rocks with high magnesium oxide, >3% potassium oxide, high sodium oxide and high nickel and chromium.
Lamprophyres occur throughout all geologic eras. Archaean examples are commonly associated with lode gold deposits. Cenozoic examples include magnesian rocks in Mexico and South America, and young ultramafic lamprophyres from Gympie in Australia with 18.5% MgO at ~250 Ma.
Petrology
Modern science treats lamprophyres as a catch-all term for ultrapotassic mafic igneous rocks which have primary mineralogy consisting of amphibole or biotite, and with feldspar in the groundmass.Lamprophyres are not amenable to classification according to modal proportions, such as the system QAPF due to peculiar mineralogy, nor compositional discrimination diagrams, such as TAS because of their peculiar geochemistry. They are classified under the IUGS Nomenclature for Igneous Rocks separately; this is primarily because they are rare, have peculiar mineralogy and do not fit classical classification schemes. For example, the TAS scheme is inappropriate due to the control of mineralogy by potassium, not by calcium or sodium.
Mitchell has suggested that rocks belonging to the "lamprophyre facies" are characterized by the presence of phenocrysts of mica and/or amphibole together with lesser clinopyroxene and/or melilite set in a groundmass which may consist of plagioclase, alkali feldspar, feldspathoids, carbonate, monticellite, melilite, mica, amphibole, pyroxene, perovskite, Fe-Ti oxides and glass.
Classification schemes which include genetic information, may be required to properly describe lamprophyres.
Genesis
Rock considered lamprophyres are part of a "clan" of rocks, with similar mineralogy, textures and genesis. Lamprophyres are similar to lamproites and kimberlites. While modern concepts see orangeites, lamproites and kimberlites as separate, a vast majority of lamprophyres have similar origins to these other rock types.Mitchell considered the lamprophyres as a "facies" of igneous rocks created by a set of conditions. Either scheme may apply to some, but not all, occurrences and variations of the broader group of rocks known as lamprophyres and melilitic rocks.
Leaving aside complex petrogenetic arguments, it is fair to say that the essential components in lamprophyre genesis are;
- high depth of melting, which yields more mafic magmas;
- low degrees of partial melting, which yields magmas rich in the alkalis ;
- lithophile element enrichment, high Ni and Cr,
- high potassium and sodium concentrations
- some form of volatile enrichment, to provide the biotite and amphibole mineralogy
- lack of fractional crystallisation
- high Mg#
Petrography
Lamprophyres are a group of rocks containing phenocrysts, usually of biotite and amphibole, and pyroxene, but not of feldspar. They are thus distinguished from the porphyries and porphyrites in which the feldspar has crystallized in two generations. They are essentially dike rocks, occurring as dikes and thin sills, and are also found as marginal facies of plutonic intrusions. They are usually dark in color, owing to the abundance of ferro-magnesian silicates, of high specific gravity and liable to decomposition. For these reasons they have been defined as a melanocrate series ; and they are often accompanied by a complementary leucocrate series such as aplites, porphyries and felsites.Biotite and amphibole are panidiomorphic; all are euhedral, well formed. Feldspar is restricted to the ground mass. In many lamprophyres the pale quartz and felspathic ingredients tend to occur in rounded spots, or ocelli, in which there has been progressive crystallization from the margins towards the center. These spots may consist of radiate or brush-like feldspars or of quartz and feldspar. A central area of quartz or of analcite probably represents an original miarolitic cavity infilled at a later period.
The presence or absence of the four dominant minerals, orthoclase, plagioclase, biotite and hornblende, determines the species:
- Minette contains biotite and orthoclase.
- Kersantite contains biotite and plagioclase.
- Vogesite contains hornblende and orthoclase.
- Spessartite contains hornblende and plagioclase. Each variety of lamprophyre may and often does contain all four minerals but is named according to the two which predominate.
Ocellar structure is common; the ocelli consist mainly of orthoclase and quartz, and may be up to one quarter of an inch in diameter. Another feature of these rocks is the presence of large foreign crystals, or xenocrysts, of feldspar and of quartz. Their forms are rounded, indicating partial resorption and the quartz may be surrounded by corrosion borders of minerals such as augite and hornblende produced where the magma is attacking the crystal.
Lamprophyres traditionally have been defined as:
- normally occurring as porphyritic dikes
- containing matrix restricted feldspars and/or feldspathoids if present
- biotite or phlogopite is an essential mineral phase
- commonly extensively hydrothermally altered
- may contain primary calcite, zeolites and other more typically hydrothermal minerals
- higher than normal contents of K2O and/or Na2O, H2O, CO2, S, P2O5, and Ba
Nomenclature
The naming and classification of lamprophyres has had several revisions, and much argument within the geological community. Nicholas Rock and colleagues devoted much time to a complicated descriptive system of nomenclature which took after a series of nomenclature based on regional examples of the very diverse mineralogical expression of lamprophyres. This system was based on a somewhat provincial, rustic system of naming after French villages nearby were found the first described examples of various species of lamprophyre.Modern nomenclature has been derived from an attempt to constrain some genetic parameters of lamprophyre genesis. This has, by and large, dispensed with the previous provincial names of lamprophyre species, in favor of a mineralogical name. The old names are still used for convenience.
Vogesite
Vogesite was first described from the Vosges mountains, France, where rocks of this type were described in the early 20th century.Minette
A historical view of minette was provided by Johannsen. He wrote that the name was "... used by the miners in the Vosges apparently for oolitic or granular iron ore, and possibly derived from the valley of Minkette, where it occurs...."Examples include minettes in the Navajo Volcanic Field of the Colorado Plateau and in the Mexican Volcanic Belt.
Distribution
Lamprophyres are usually associated with voluminous granodiorite intrusive episodes. They occur as marginal facies to some granites, though usually as dikes and sills marginal to and crosscutting the granites and diorites. In other districts where granites are abundant no rocks of this class are known. It is rare to find only one member of the group present, but minettes, vogesites, kersantites, etc., all appear and there are usually transitional forms.Lamprophyres are also known to be spatially and temporally associated with gold mineralisation, for example orogenic gold deposits. Rock considered lamphrophyres to be possible source rocks for the gold, but this view is not generally supported. The more reasonable explanation for the correlation is that lamprophyres, representing "wet" melts of the asthenosphere and mantle, correlate with a period of high fluid flow from the mantle through the crust, during subduction-related metamorphism, which drives gold mineralisation.
Non-melilitic lamprophyres are found in many districts where granites and diorites occur, such as the Scottish Highlands and Southern Uplands of Scotland; the Lake District of northwest England; Ireland; the Vosges Mountains of France; the Black Forest and Harz mountain regions of Germany; Mascota, Mexico; Jamaica and in certain locations of British Columbia, Canada.