Ladder operator
In linear algebra, a raising or lowering operator is an operator that increases or decreases the eigenvalue of another operator. In quantum mechanics, the raising operator is sometimes called the creation operator, and the lowering operator the annihilation operator. Well-known applications of ladder operators in quantum mechanics are in the formalisms of the quantum harmonic oscillator and angular momentum.
Terminology
There is some confusion regarding the relationship between the raising and lowering ladder operators and the creation and annihilation operators commonly used in quantum field theory. The creation operator ai† increments the number of particles in state i, while the corresponding annihilation operator ai decrements the number of particles in state i. This clearly satisfies the requirements of the above definition of a ladder operator: the incrementing or decrementing of the eigenvalue of another operator.Confusion arises because the term ladder operator is typically used to describe an operator that acts to increment or decrement a quantum number describing the state of a system. To change the state of a particle with the creation/annihilation operators of QFT requires the use of both an annihilation operator to remove a particle from the initial state and a creation operator to add a particle to the final state.
The term "ladder operator" is also sometimes used in mathematics, in the context of the theory of Lie algebras and in particular the affine Lie algebras, to describe the su subalgebras, from which the root system and the highest weight modules can be constructed by means of the ladder operators. In particular, the highest weight is annihilated by the raising operators; the rest of the positive root space is obtained by repeatedly applying the lowering operators.
General formulation
Suppose that two operators X and N have the commutation relation,for some scalar c. If is an eigenstate of N with eigenvalue equation,
then the operator X acts on in such a way as to shift the eigenvalue by c:
In other words, if is an eigenstate of N with eigenvalue n then is an eigenstate of N with eigenvalue n + c or it is zero. The operator X is a raising operator for N if c is real and positive, and a lowering operator for N if c is real and negative.
If N is a Hermitian operator then c must be real and the Hermitian adjoint of X obeys the commutation relation:
In particular, if X is a lowering operator for N then X† is a raising operator for N and vice versa.
Angular momentum
A particular application of the ladder operator concept is found in the quantum mechanical treatment of angular momentum. For a general angular momentum vector, J, with components, Jx, Jy and Jz we define the two ladder operators, J+ and J–:where i is the imaginary unit.
The commutation relation between the cartesian components of any angular momentum operator is given by
where εijk is the Levi-Civita symbol and each of i, j and k can take any of the values x, y and z. From this the commutation relations between the ladder operators and Jz can easily be obtained:
The properties of the ladder operators can be determined by observing how they modify the action of the Jz operator on a given state:
Compare this result with:
Thus we conclude that is some scalar multiplied by,
This illustrates the defining feature of ladder operators in quantum mechanics: the incrementing of a quantum number, thus mapping one quantum state onto another. This is the reason that they are often known as raising and lowering operators.
To obtain the values of α and β we first take the norm of each operator, recognizing that J+ and J− are a Hermitian conjugate pair,
The product of the ladder operators can be expressed in terms of the commuting pair J2 and Jz,
Thus we can express the values of |α|2 and |β|2 in terms of the eigenvalues of J2 and Jz,
The phases of α and β are not physically significant, thus they can be chosen to be positive and real. We then have:
Confirming that m is bounded by the value of j we have:
The above demonstration is effectively the construction of the Clebsch-Gordan coefficients.
Applications in atomic and molecular physics
Many terms in the Hamiltonians of atomic or molecular systems involve the scalar product of angular momentum operators. An example is the magnetic dipole term in the hyperfine Hamiltonian,where I is the nuclear spin.
Angular momentum algebra can often be simplified by recasting it in the spherical basis. Using the notation of spherical tensor operators, the "-1", "0" and "+1" components of J ≡ J are given by,
From these definitions it can be shown that the above scalar product can be expanded as
The significance of this expansion is that it clearly indicates which states are coupled by this term in the Hamiltonian, that is those with quantum numbers differing by mi = ±1 and mj = ∓1 only.
Harmonic oscillator
Another application of the ladder operator concept is found in the quantum mechanical treatment of the harmonic oscillator. We can define the lowering and raising operators asThey provide a convenient means to extract energy eigenvalues without directly solving the system's differential equation.
Hydrogen-like atom
Another application of the ladder operator concept is found in the quantum mechanical treatment of the electronic energy of hydrogen-like atoms and ions.
We can define the lowering and raising operators
where is the angular momentum, is the linear momentum, is the reduced mass of the system, is the electronic charge, and is the atomic number of the nucleus.
Analogous to the angular momentum ladder operators, one has and.
The commutators needed to proceed are:
and
Therefore,
and
so
where the "?" indicates a nascent quantum number which emerges from the discussion.
Given the Pauli equations
Pauli Equation IV:
and Pauli Equation III:
and starting with the equation
and expanding,
one obtains,
which leads to the infamous
implying that, where is the traditional quantum number.