Fuel dyes


Fuel dyes are dyes added to fuels, as in some countries it is required by law to dye a low-tax fuel to deter its use in applications intended for higher-taxed ones. Untaxed fuels are referred to as "dyed", while taxed ones are called "clear" or "white".
Aviation gasoline is dyed, both for tax reasons as well as safety.

Types of Dyes

The dyes used have to be soluble in the fuels they are added to and therefore in hydrocarbon-based nonpolar solvents. Red dyes are often various diazo dyes, e.g., Solvent Red 19, Solvent Red 24, and Solvent Red 26. Anthraquinone dyes are used for green and blue shades, e.g., Solvent Green 33, Solvent Blue 35 and Solvent Blue 26.
The pure dyes found in modern liquid petroleum dyes are essentially longer alkyl side chain forms of traditional dyes and normally multiple chain length variations of the chromophore are found within a typical commercial liquid petroleum dye.
For instance, Sudan Red 462 is essentially Solvent Red 19, with the ethyl side chain replaced by either a 2-ethylhexyl or a tridecyl side chain. The longer branched side chains improve solubility dramatically, but in some cases the high solubility prevents the dye being isolated as a crystal, except at very low temperatures.
The high solubility liquid dyes originated with Morton International and BASF as the primary inventors.
For instance, Morton International created Solvent Blue 98 as a high solubility form of Solvent Blue 35. BASF created Solvent Blue 79 as its high solubility form of Solvent Blue 35.
In some cases it is possible, with normal solvents—e.g., xylene—to prepare stable solutions at 65% "solids" content. The original powder dye form of the chromophore would not be soluble beyond 2% in xylene.
Only a few refineries worldwide still use powder dyes for colouring fuels, as ultimately they are still lower cost per active molecule of dye chromophore than the modified forms. They have significant handling issues and health and safety issues that inherently arise from the handling of azo dyes. It is advantageous to mix a liquid with a liquid instead of handling powdered dyes into a liquid.

Fuel dye in the European Union

After August 2002, all European Union countries became obliged to add about 6 mg/L of Solvent Yellow 124, a dye with structure similar to Solvent Yellow 56, to heating fuel. This dye can be easily hydrolyzed with acids, splitting off the acetal group responsible for its solubility in nonpolar solvents, and yielding a water-soluble form. Like a similar methyl orange dye, it changes color to red in acidic pH. It can be easily detected in the fuel at levels as low as 0.3 ppm by extraction to a diluted hydrochloric acid, allowing detection of the red diesel added into motor diesel in amounts as low as 2–3%.
The European Union has announced that has found a new and better marker to replace Solvent Yellow 124.

United Kingdom

In the United Kingdom, "red diesel" is dyed gas oil for registered agricultural or construction vehicles such as tractors, excavators, cranes and some other non-road applications such as boats. Red diesel carries a significantly reduced tax levy compared to un-dyed diesel fuel used in ordinary road vehicles. As red diesel is widely available in the UK, the authorities regularly carry out roadside checks. Unauthorised use incurs heavy fines but despite this, spot checks have occasionally found as many as one in five motorists using red diesel.
Red diesel can also be used in road vehicles which are registered as off-road with the DVLA provided they are only used on private land. On 14 July 2014, the European Commission announced it was referring the United Kingdom to the European Court of Justice over the use of red-diesel in propelling private pleasure craft on water. It believes the UK is not properly applying EU regulations for the fiscal marking of fuels.
On 18 November 2014, a new measure to combat fuel laundering should result in the illegal trade being "virtually eliminated" in the United Kingdom, according to HM Revenue and Customs. A new dye will be introduced in April 2015 in the United Kingdom and the Republic of Ireland.

Carbon offset red diesel

Carbon offset red diesel is, as of 2014, available in the UK. It is marketed as an environmentally friendly alternative to regular red diesel. There is an extra cost incurred when purchasing carbon offset red diesel, however some suppliers of the fuel are donating the extra cost to projects aimed at lowering carbon emissions, meaning they make no extra profit from the sale of the fuel.

Finland

Low-tax dyed fuel oil, is available in many rural petrol stations in Finland, primarily intended for certain types of non-road vehicles such as tractors and driveable construction vehicles. Until 2002, furfural was used to dye fuel oil in Finland, when it was replaced with Solvent Yellow 124. Since 2008, boats and pleasure craft are no longer legally allowed to use low-tax fuel oil, instead taxable diesel must be used for fuel.

Poland

Currently there are no naked-eye visible dyes in car fuels sold in Poland. However, during the time of Communist Party rule, the state-owned CPN fuel monopoly dyed leaded gasolines in the following colors: 78 – blue, 86 – green, 94 – yellow, 98 – red. Diesel fuel, although unleaded, was also dyed a brown color.

Fuel dye in North America

In the United States of America, the Environmental Protection Agency mandates use of a red dye to identify fuels for off-road use. Solvent Red 26 is used in the United States as a standard, though it is often replaced with Solvent Red 164, which is similar to Solvent Red 26 but with longer alkyl chains. The Internal Revenue Service regulation mandates use of the same red dyes, in fivefold concentration, for tax-exempt diesel fuels such as heating oil; their argument for the higher dye content is to allow detection even when diluted with "legal" fuel. Detection of red-dyed fuel in the fuel system of an on-road vehicle will incur substantial penalties.

Fuel laundering

gangs may "launder" low-price dyed fuel, removing the dye and selling it illegally to unsuspecting motorists at the higher price of undyed fuel. Paramilitary groups connected to political unrest in Northern Ireland have established laundering plants on both sides of the Irish border. In 2004, Northern Irish police discovered an illegal facility capable of removing the dye from 12 million litres of fuel per year. In 2009, customs officials shut down a plant capable of removing the dye from 6.5 million litres of fuel per year. In 2011, a plant capable of processing 30 million litres was discovered.

Fuel theft

Fuel is being dyed by companies such as Bord na Móna in Ireland in an effort to combat the widespread theft of fuel.

Dyes Used By Country

Some dyes required in some countries are listed here:
CountryFuelDye
Regular unleaded petrolundyed - clear to yellow
Premium unleaded petrolundyed - clear to yellow
Heating oilany red dye and Solvent Yellow 124
Off-road fuel red/purple dye
Marine gasolineany red dye
Heating oilany red dye
Heating oilSolvent Yellow 124
Diesel for construction and agricultureSolvent Yellow 124
Diesel Solvent Red 24 and Solvent Yellow 124
Marine dieselSolvent Blue 35
azobenzene-4-amine. SIA “Straujupīte” for diesel labeling is using no more than 0.2% of sulfur content.]
Diesel is labeled by adding one of the coloring matters to 1000 liters of oil products::
  • naphthyl-2-amine – at least 5.0 grams;
fiscal marker - chemical N-ethyl-N- -4- aniline - at least 6.0 grams, and no more than 9.0 grams; on 1000l
blue colorant 1,4-bis -9,10-anthraquinone or any other equivalent blue coloring - at least 7.0 grams on 1000l
Heating oilAutomate Red NR or similar
Agricultural dieselAutomate Blue 8 GHF or similar
Heating oilSolvent Yellow 124 + 4.1 gr/litre Solvent Red 19 or 5.3 gr tolyazotolyazo-ethylhexylbetanaphthylamine or 6.1 gr tolyazotolyazo-tridecylbetanaphthylamine & similar
Heating oilany red dye
Marine dieselany black dye
Heating oilFerrocene
Pertalite Green dye
PERTAMAX Blue dye
PERTAMAX Turbo Red dye
Gas oilgreen dye = Solvent Yellow 124 and Anthraquinone Blue dye equivalent to Solvent Blue 35 and ACCUTRACE S10 -4-methanetriyl)tribenzene
KeroseneSolvent Red 19, Solvent Yellow 124 and ACCUTRACE S10 -4-methanetriyl)tribenzene
Heating oilSolvent Red 161
Gas oilSolvent Green 32 or 33 and Solvent Yellow 124
Agricultural dieselany red dye and Solvent Yellow 124
Agricultural dieselany green dye
Agricultural dieselSolvent Blue 35
Heating oilSolvent Red 19 and similar
Agricultural dieselany red dye + Solvent Yellow 124: Orden PRE/1724/2002 of the 5th of July.
Heating oilany blue dye + Solvent Yellow 124: Orden PRE/1724/2002 of the 5th of July.
Heating oilSolvent Blue 35, Solvent Blue 79, Solvent Blue 98 and Solvent Yellow 124
Gasoline 95yellow dye
Gasoline 91red dye
Gas oil Solvent Red 24, quinizarin, Solvent Yellow 124 and -4-methanetriyl)tribenzene
Rebated keroseneCoumarin, Solvent Yellow 124 and -4-methanetriyl)tribenzene
many rebatedSolvent Yellow 124
low-tax fuels, high-sulfur fuelsSolvent Red 26 3.9lbs per 1000 barrels, Solvent Red 164
WorldwideAviation gasoline 80/87red dye
WorldwideAviation gasoline 82ULpurple dye
WorldwideAviation gasoline 100LLblue dye
WorldwideAviation gasoline 100/130green dye