FKM is a family of fluoroelastomer materials defined by the ASTM International standard D1418. It is equivalent to FPM by ISO/DIN 1629 standard. All FKMs contain vinylidene fluoride as a monomer. Originally developed by DuPont, FKMs are today also produced by Daikin Chemical, 3M's Dyneon, Solvay Specialty Polymers, HaloPolymer and several Chinese manufacturers. Viton® is now manufactured by Chemours. Fluoroelastomers are more expensive than neoprene or nitrile rubber elastomers. They provide additional heat and chemical resistance. FKMs can be divided into different classes on the basis of either their chemical composition, their fluorine content or their crosslinking mechanism.
Types
On the basis of their chemical composition FKMs can be divided into the following types:
Type 2 FKMs are composed of VDF, HFP, and tetrafluoroethylene. Terpolymers have a higher fluorine content compared to copolymers, which results in better chemical and heat resistance. Compression set and low temperature flexibility may be affected negatively.
Type 3 FKMs are composed of VDF, TFE, and perfluoromethylvinylether. The addition of PMVE provides better low temperature flexibility compared to copolymers and terpolymers. Typically, the fluorine content of type 3 FKMs ranges from 62 to 68 weight percent.
Type 4 FKMs are composed of propylene, TFE, and VDF. While base resistance is increased in type 4 FKMs, their swelling properties, especially in hydrocarbons, are worsened. Typically, they have a fluorine content of about 67 weight percent.
Type 5 FKMs are composed of VDF, HFP, TFE, PMVE, and Ethylene. Type 5 FKM is known for base resistance and high temperature hydrogen sulfide resistance.
A useful overview of different types of FKM-compounds is listed .
Crosslinking mechanisms
There are three established crosslinking mechanisms used in the curing process of FKMs.
Diamine crosslinking using a blocked diamine. In the presence of basic media VDF is vulnerable to dehydrofluorination which enables the addition of the diamine to the polymer chain. Typically magnesium oxide is used to neutralize the resulting hydrofluoric acid and rearrange into magnesium fluoride and water. Although rarely used today, diamine curing provides superior rubber-to-metal bonding properties as compared with other crosslinking mechanisms. The diamine's capability to be hydrated makes the diamine crosslink vulnerable in aqueous media.
Ionic crosslinking was the next step in curing FKMs. This is today the most common crosslinking chemistry used for FKMs. It provides superior heat resistance, improved hydrolytic stability and better compression set than diamine curing. In contrast to diamine curing the ionic mechanism is not an addition mechanism but an aromatic nucleophilic substitution. Dihydroxy aromatic compounds are used as the crosslinking agent and quaternary phosphonium salts are typically used to accelerate the curing process.
Peroxide crosslinking was originally developed for type 3 FKMs containing PMVE as diamine and bisphenolic crosslinking systems can lead to cleavage in a polymer backbone containing PMVE. While diamine and bisphenolic crosslinking are ionic reactions, peroxide crosslinking is a free radical mechanism. Though peroxide crosslinks are not as thermally stable as bisphenolic crosslinks, they normally are the system of choice in aqueous and nonaqueous electrolytes.
Application of FKM：
1. Chemical Process and Petroleum Refining: This sealing product is used in mechanical seals, pumps, reactors, mixers, compressor housings, valves, meters and other equipment. Usually used as a seat, stem packing, diaphragm and gasket. 2, analysis and process instruments: separators, diaphragms, cylindrical fittings, hoops, gaskets, etc. 3. Semiconductor manufacturing 4. Food and pharmaceutical 5. Aviation and aerospace
