Delay composition Delay composition , also called delay charge or delay train , is a pyrotechnic composition , a sort of pyrotechnic initiator , a mixture of oxidizer and fuel that burns in a slow , constant rate that should not be significantly dependent on temperature and pressure. Delay compositions are used to introduce a delay into the firing train , e.g. to properly sequence firing of fireworks , to delay firing of ejection charges in e.g. model rockets , or to introduce a few seconds of time between triggering a hand grenade and its explosion . Typical delay times range between several milliseconds and several seconds. A popular delay charge is a tube of pressed black powder . The mechanical assembly prevents the outright detonation of the charge. While delay compositions are principally similar to other fuel-oxidizer compositions, larger grain sizes and less aggressively reacting chemicals are used. Many of the compositions generate little or no gas during burning. Typical materials used are: Fuels : silicon , boron , manganese , tungsten , antimony , antimony trisulfide , zirconium , zirconium-nickel alloy, zinc , magnesium , etc . Oxidizers : lead dioxide , iron oxides , barium chromate , lead chromate , tin oxide , bismuth oxide , barium sulfate , potassium perchlorate , etc. Additives to cool down the flame and slow down the reaction can be employed; inert materials or coolants like titanium dioxide , ground glass , chalk , sodium bicarbonate , etc. are common. The burn rates are dependent on: nature of fuel - fuels that release more heat burn faster nature of oxidizer - oxidizers that require less heat to decompose burn faster the composition ratio - stoichiometric mixtures burn the fastest, also slight excess of metallic fuel also increases burn rate , probably due to heat transfer particle sizes - smaller particles burn faster, but too small particles may lead to incomplete or interrupted burn due to too narrow heating zone mechanical assembly and housing - charge diameter and thermal conductivity of housing influence lateral heat losses ambient temperature - ideally this dependence is very low but extremely low or extremely high temperatures may have influence Examples of some compositions are: black powder with addition of inert material, e.g. chalk or sodium bicarbonate lead oxide with silicon, burning at 1.5–2 cm/s red lead with silicon, burning at intermediate rate lead oxide with silicon, burning at 5–6 cm/s potassium permanganate with antimony, very slow Manganese Delay Composition: manganese with lead chromate and barium chromate Tungsten Delay Composition: tungsten with barium chromate and potassium perchlorate Zirconium Nickel Alloy Delay Composition: zirconium-nickel alloy with barium chromate and potassium perchlorate. boron with barium chromate
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