Chanabayaite Chanabayaite is the first recognized triazolate mineral , having the following formula: Cu2 4 . Minor iron admixture is also present. It is also one of a few currently known minerals containing ammine groups, including also ammineite , joanneumite and shilovite. All the minerals are rare and were found in a single guano deposit in Chile , called Pabellón de Pica . A similar natural phase, formula NaCu2 Cl3 2 2 ·4H2 O, likely a precursor of chanabayaite, is described by Zubkova et al . 2016.Crystal structure The main features of the crystal structure of chanabayaite are: copper forms octahedra, part of which share corners 1,2,4-triazolate anions link the octahedraAssociation halite , joanneumite, nitratine , salammoniac and paragenetically-unrelated chalcopyrite . Chalcopyrite is present in an amphibole- and plagioclase-bearing gabbro, that contacts the guano deposit.Formation Three suggested processes account for the formation of chanabayaite: leaching of sodium from the precursor phase leaching of chlorine from the precursor phase partial dehydratation of the precursor phase
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