The Boudouard reaction, named after Octave Leopold Boudouard, is the redox reaction of a chemical equilibriummixture of carbon monoxide and carbon dioxide at a given temperature. It is the disproportionation of carbon monoxide into carbon dioxide and graphite or its reverse: The Boudouard Reaction to form carbon dioxide and carbon is exothermic at all temperatures. However, the standard enthalpy of the Boudouard reaction becomes less negative with increasing temperature, as shown to the side. While the formation enthalpy of is higher than that of, the formation entropy is much lower. Consequently, the standard free energy of formation of from its component elements is almost constant and independent of the temperature, while the free energy of formation of decreases with temperature. At high temperatures, the forward reaction becomes endergonic, favoring the reverse reaction toward CO, even though the forward reaction is still exothermic. The effect of temperature on the extent of the Boudouard reaction is indicated better by the value of the equilibrium constant than by the standard free energy of reaction. The value of log10 for the reaction as a function of temperature in Kelvin is approximately: has a value of zero at. The implication of the change in Keq with temperature is that a gas containing may form elemental carbon if the mixture cools below a certain temperature. The thermodynamic activity of carbon may be calculated for a / mixture by knowing the partial pressure of each species and the value of Keq. For instance, in a high temperature reducing environment, such as that created for the reduction of iron oxide in a blast furnace or the preparation of carburizing atmospheres, carbon monoxide is the stable oxide of carbon. When a gas rich in is cooled to the point where the activity of carbon exceeds one, the Boudouard Reaction can take place. Carbon monoxide then tends to disproportionate into carbon dioxide and graphite, which forms soot. In industrial catalysis, this is not just an eyesore; sooting can cause serious and even irreversible damage to catalysts and catalyst beds. This is a problem in the catalytic reforming of petroleum and the steam reforming of natural gas. The reaction is named after the French chemist, Octave Leopold Boudouard, who investigated this equilibrium in 1905.
Uses
Although the damaging effect of carbon monoxide on catalysts is undesirable, this reaction has been used in producing graphite flakes, filamentous graphite and lamellar graphite crystallites, as well as producing carbon nanotubes. In graphite production, catalysts used are molybdenum, magnesium, nickel, iron and cobalt, while in carbon nanotube production, molybdenum, nickel, cobalt, iron and Ni-MgO catalysts are used. The Boudouard reaction is an important process inside a blast furnace. The reduction of iron oxides is not achieved by carbon directly, as reactions between solids are typically very slow, but by carbon monoxide. The resulting carbon dioxide undergoes a Boudouard reaction upon contact with coke carbon.
