Historically, both nations were host to great indigenous cultures; the Aztecs and Mayas in Mexico and the Incas and Aymaras in Bolivia. Both countries were part of the Spanish Empire until the early 19th century. Mexico was part of Viceroyalty of New Spain while Bolivia was at first part of the Viceroyalty of Peru and then in 1776, it became part of the Viceroyalty of the Río de la Plata. Soon after independence, both nations established diplomatic relations. In 1831, Mexico sent its first concurrent ambassador to Bolivia based in Buenos Aires, Argentina. In September 1902, the first Mexican consulate-general was opened in La Paz and thus the first official diplomatic mission of Mexico in the country. In 1934, Bolivia opened its first diplomatic mission in Mexico City. In February 1939, both diplomatic missions were elevated to embassies in each other's capitals, respectively. Between 1964-1982, Bolivia was ruled by a military junta. During this time period, diplomatic relations between Bolivia and Mexico became tense. Between 1967 and 1980, the Mexican embassy in La Paz provided asylum to 260 Bolivian citizens during that time period. The most prominent asylee at the embassy was Dr. Antonio Arguedas Mendieta, a Bolivian national and former Minister of the Interior who in 1968 arranged for copies of Che Guevara's captured diaries to be smuggled to Havana, Cuba after his death in Bolivia in October 1967. When the government of President René Barrientos discovered the documents to be missing, it was discovered that Dr. Arguedas Mendieta was a CIA agent who had been recruited to destroy Che Guevara's forces in the country, but he was soon to become disenchanted with the Bolivian government and decided to send Guevara's diaries to Cuba. Dr. Arguedas Mendieta was accused by the Bolivian State for selling state secrets and in July 1969, Dr. Arguedas Mendieta sought asylum in the Mexican embassy where he remained until May 1970 when he was granted safe-conduct out of Bolivia to Mexico. In 1960, Mexican President Adolfo López Mateos had planned to visit Bolivia, however, his visit was suspended by force majeure. In 1963, President Víctor Paz Estenssoro became the first Bolivian head-of-state to visit Mexico. In 1990, President Carlos Salinas de Gortari became the first Mexican head-of-state to pay an official visit to Bolivia. In September 1994, Bolivia and Mexico signed a free trade agreement, however, in June 2010, Bolivian President Evo Morales cancelled the free trade agreement with Mexico. In January 2019, Bolivian Foreign Minister, Diego Pary, paid a visit to Mexico and met with Mexican Foreign Minister Marcelo Ebrard. During the visit, Mexico stated that it intends to remove visa requirements for Bolivian citizens for touristic purposes.
During the 2019 Bolivian general election, the Organization of American States conducted an audit that found "clear manipulation" in the election and significant irregularities overseen by the Electoral Commission. Following protests, President Morales agreed to hold fresh elections on 10 November 2019; however, soon afterwards President Morales and his vice president, Álvaro García Linera, resigned from office after losing support from the police and military. The Mexican government offered President Morales asylum in Mexico which he accepted the following day before boarding a Mexican Air Force plane to Mexico and arrived in Mexico City on 12 November 2019. On 12 December 2019, Evo Morales left Mexico for Argentina after the swearing in of the new President, Alberto Fernández, where he was granted asylum. Since the arrival of Evo Morales to Mexico, relations between Mexico and the new Bolivian government of interim-President Jeanine Áñez have been tense. The Mexican embassy in La Paz has opened its ambassador's residence to various former associates of Evo Morales, and this has led to protests from angry Bolivians who oppose the ex-president. The Mexican government has accused Bolivian authorities of harassing and intimidating its diplomatic staff, and has asked the International Court of Justice to mediate in the dispute. On 30th December, a few days after two Spanish diplomats visited the Mexican embassy's residence to pay a courtesy visit; the Bolivian government expelled the Mexican Ambassador, María Teresa Mercado, from the country along with two Spanish diplomats and accused both governments of having ulterior "hostile" motives, thus creating a diplomatic dispute between the Bolivian government with Mexico and Spain.
Both nations have signed several bilateral agreements such as an Extradition Treaty; Treaty for the Execution of Criminal Sentences; Agreement of Cooperation to Combat Drug Trafficking and Drug dependency; Agreement on Technical and Scientific Cooperation; Air Transportation Agreement; Agreement in Education, Sports and Cultural Cooperation; Treaty of Cooperation of Legal Aid in Criminal Matters; Agreement of Cooperation in Mutual Administrative Assistance and Exchange of Information in Customs Matters.
Trade
In September 1994, a free trade agreement was signed between the two nations, however, in June 2010 Bolivian President Evo Morales cancelled the free trade agreement with Mexico. In 2018, bilateral trade between Bolivia and Mexico amounted to $180 million USD. Bolivia's exports to Mexico include: quinoa; tin without alloy; helmets; plates and cylinders for hats; bovine skins; lumber; and silver minerals and their concentrates. Mexico's exports to Bolivia include: tractors; cylinder for vehicles; other motor vehicles for the transport of goods; and expandable polystyrene. Mexican multinational companies such as Gruma and Grupo Bimbo operate in Bolivia.