Bauxite


Bauxite is a sedimentary rock with a relatively high aluminium content. It is the world's main source of aluminium and gallium. Bauxite consists mostly of the aluminium minerals gibbsite, boehmite and diaspore, mixed with the two iron oxides goethite and haematite, the aluminium clay mineral kaolinite and small amounts of anatase and ilmenite.
In 1821 the French geologist Pierre Berthier discovered bauxite near the village of Les Baux in Provence, southern France.

Formation

Numerous classification schemes have been proposed for bauxite but, as of 1982, there was no consensus.
Vadász distinguished lateritic bauxites from karst bauxite ores :
In the case of Jamaica, recent analysis of the soils showed elevated levels of cadmium, suggesting that the bauxite originates from recent Miocene ash deposits from episodes of significant volcanism in Central America.

Production and reserves

Australia is the largest producer of bauxite, followed by China. Increased aluminium recycling, which has the advantage of lowering the cost in electric power in producing aluminium, will considerably extend the world's bauxite reserves.
RankCountryProductionReserves
1Australia86,4006,000,000
2China79,0001,000,000
3Guinea57,0007,400,000
4Brazil29,0002,600,000
5India23,000660,000
6Indonesia11,0001,200,000
7Jamaica10,1002,000,000
8Russia5,650500,000
9Kazakhstan5,000160,000
10Vietnam4,1003,700,000
11South Arabia3,890200,000
12Greece1,800250,000
13Guyana1,700850,000
Other countries9,0003,740,000
World327,00030,000,000

In November 2010, Nguyen Tan Dung, the prime minister of Vietnam, announced that Vietnam's bauxite reserves might total 11,000 Mt ; this would be the largest in the world.

Processing

Bauxite is usually strip mined because it is almost always found near the surface of the terrain, with little or no overburden., approximately 70% to 80% of the world's dry bauxite production is processed first into alumina and then into aluminium by electrolysis. Bauxite rocks are typically classified according to their intended commercial application: metallurgical, abrasive, cement, chemical, and refractory.
Usually, bauxite ore is heated in a pressure vessel along with a sodium hydroxide solution at a temperature of. At these temperatures, the aluminium is dissolved as sodium aluminate. The aluminium compounds in the bauxite may be present as gibbsite, boehmite or diaspore; the different forms of the aluminium component will dictate the extraction conditions. The undissolved waste, bauxite tailings, after the aluminium compounds are extracted contains iron oxides, silica, calcia, titania and some un-reacted alumina. After separation of the residue by filtering, pure gibbsite is precipitated when the liquid is cooled, and then seeded with fine-grained aluminium hydroxide. The gibbsite is usually converted into aluminium oxide, Al2O3, by heating in rotary kilns or fluid flash calciners to a temperature in excess of. This aluminium oxide is dissolved at a temperature of about in molten cryolite. Next, this molten substance can yield metallic aluminium by passing an electric current through it in the process of electrolysis, which is called the Hall–Héroult process, named after its American and French discoverers.
Prior to the invention of this process, and prior to the Deville process, aluminium ore was refined by heating ore along with elemental sodium or potassium in a vacuum. The method was complicated and consumed materials that were themselves expensive at that time. This made early elemental aluminium more expensive than gold.